Enolization of Carbonyls
Enolization of Carbonyls
May 8, 2024
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The Fries rearrangement enables the Lewis-acid-promoted intramolecular transfer of an acyl group from an aryl ester to the aromatic ring, forming ortho- or para-acylphenols. Discovered by Karl Theophil Fries in the early 20th century, the reaction proceeds via activation of the ester by a Lewis acid followed by electrophilic aromatic substitution by the acyl group. Learn. Review. Repeat.
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The Fries rearrangement enables the Lewis-acid-promoted intramol…
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The Fries rearrangement enables the Lewis-acid-promoted intramolecular transfer of an acyl group from an aryl ester to the aromatic ring, forming ortho- or para-acylphenols. Discovered by Karl Theophil Fries in the early 20th century, the reaction proceeds via activation of the ester by a Lewis acid followed by electrophilic aromatic substitution by the acyl group. Learn. Review. Repeat.
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The Fries rearrangement enables the Lewis-acid-promoted intramol…
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The Beckmann rearrangement enables the conversion of oximes into amides or lactams via acid-promoted rearrangement with substituent migration. Developed by Ernst Otto Beckmann in the late 19th century, the reaction proceeds through activation of the oxime, rearrangement to a nitrilium intermediate, and subsequent attack of water to yield the amide. Learn. Review. Repeat.
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